Activated Bamboo Charcoal by ZnCl2 as Remazol Yellow FG Adsorbent: Isotherm, Kinetic, and Thermodynamic Studies

Authors

  • Manuntun Manurung Udayana University
  • Ni Made Suaniti Udayana University
  • Oka Ratnayani Udayana University

DOI:

https://doi.org/10.21776/ub.jpacr.2024.013.02.3311

Keywords:

The aim of this study was to determine the isotherm, kinetics, and thermodynamics of remazol yellow FG dye adsorption by ZnCl2-activated bamboo charcoal. The research was started by making charcoal from bamboo stems, then the quality was checked against S

Abstract

The aim of this study was to determine the isotherm, kinetics, and thermodynamics of remazol yellow FG dye adsorption by ZnCl2-activated bamboo charcoal. The research was started by making charcoal from bamboo stems, then the quality was checked against SNI. Adsorption isotherms were tested against Langmuir and Freundlich models. The adsorption kinetics were examined against pseudo-1st and pseudo-2nd orders and thermodynamic parameters were determined by measuring the values of enthalpy (∆Ho), entropy (∆So), and free energy (∆Go). The values of ∆Ho, ∆So, and ∆Go are -29.747 KJ/mol, -93.798 J/mol, and -1.327 KJ/mol respectively. The adsorption of remazol yellow FG by activated bamboo charcoal was spontaneous.

 

Keywords: adsorption, kinetics, chromium, bamboo charcoal, thermodynamics

Author Biographies

  • Manuntun Manurung, Udayana University
    Chemistry Study Program, Faculty of Mathematics and Natural Sciences, Udayana University, Jalan Kampus Jimbaran, Bali-Indonesia
  • Ni Made Suaniti, Udayana University
    Magister Program, Faculty of Mathematics and Natural Sciences, Udayana University, Jalan P.B Sudirman, Denpasar, Bali-Indonesia
  • Oka Ratnayani, Udayana University

    Chemistry Study Program, Faculty of Mathematics and Natural Sciences, Udayana University, Jalan Kampus Jimbaran, Bali-Indonesia

References

[1] Penggunaan Kain Tenun Endek Bali/ Kain Tenun Tradisional Bali. Surat Edaran Gubernur Bali Nomor 4 Tahun 2021.

[2] Puspita M, Lutfi Firdaus M, Nurhamidah., ALOTROP J. Pendidik. Dan Ilmu Kim.. 2017;1(1):75–9.

[3] Sari MFP, Loekitowati P, Mohadi R.. J. Nat. Resour. Environ. Manag [Internet]. 2017 Apr 1;7(1):37–40. Available from: http://journal.ipb.ac.id/index.php/jpsl/article/view/13431

[4] Ahmad MA, Herawan SG, Yusof AA. Journal of Mechanical Engineering and Sciences(JMES), 2014 Dec 1;7(1):1085–93.DOI:https://dx.doi.org/10.15282 /jmes.7.2014 .7.0105.

[5] Firdaus ML, Krisnanto N, Alwi W, Muhammad R, Serunting MA. Aceh International Journal of Science and Technology. 2017 Apr 8;6(1):1-7.

[6] Ekpete OA, Marcus AC, Osi V. Hindawi Journal of Chemistry. 2017; ID 8635615;1-6.

[7] Manurung M, Sahara E, Sihombing PS., Jurnal Kimia (Journal of Chemistry). 2019;13(1):16–21.

[8] Sari RA, Firdaus ML, Elvia R. ALOTROP J. Pendidik. Dan Ilmu Kim. 2017;1(1):10–14.

[9] Hameed BH, Din ATM, Ahmad AL. J. Hazard. Materials. 2007 Mar 22;141(3):819–25.

[10] Latupeirissa J, Tanasale MFJDP, Musa H. Indo. J. Chem. Res. 2018. 6 (1) : 12-21

[11] Arang Aktif Teknis [Internet]. Badan Standardisasi Nasional. 1995 [cited 2022 Dec 10]. Available from: http://sispk.bsn.go.id/SNI/DetailSNI/4132

[12] Ma Y, Wang Q, Wang X, Sun X, Wang X. Journal of Porous Materials. 2015 Feb 1;22(1):157–69.

[13] Du X, Zhao W, Ma S, Ma M, Qi T, Wang Y., Ionics (Kiel). 2016 Apr 1;22(4):545–53.

[14] Pattananandecha T, Ramangkoon S, Sirithunyalug B, Tinoi J, Saenjum C., International Journal of Applied Pharmaceutics. 2019 Jan 1;11(1):255–60. DOI: https://dx.doi.org /10.22159 /ijap.2019 v 11i1.30637

[15] Kristianto H, Alexander J, Prasetyo S, Sugih AK., Molekul. 2022 Mar 16;17(1):49–59.

[16] Atkins PW. Physical Chemistry 4th Edition. Oxford University; 1990.

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Published

2024-08-26